NTRCA college written syllabus

E:\NTRCA\Exam\17th Exam'20\Written\Syllabus\Written_College level_17th Exam-2020 (1-52 code) (Main).doc    25 
Assessment Targets 
The candidate will be able to... 
Contents Marks 
complex compounds. 
 Explain the 
properties of complex compounds. 
 Explain the split of 
the d-orbital. 
 Justify the stability of 
6-coordination numbered complexes. 
 Illustrate the bonding 
structure in complex compounds. 
structures and Isomers in coordination 
Coordination compounds, ligands, types 
of ligands, the nomenclature of 
coordination compounds, 18-electron rule, 
isomerism in coordination compounds, 
types of isomerism, the stereochemistry of 
4 and 6 - coordination complexes, chelate 
complexes, inner complexes, application 
of coordination complexes. 
Bonding in coordination compounds 
Coordination bond, Werner postulates and 
its limitation, Sidwick’s electronic concept 
and its limitation, crystal field theory, 
orbital splitting in octahedral, tetrahedral 
and square planner complexes, magnitudes 
of 10Dq, factors affecting the magnitude 
of 10Dq, applicati on of crystal field 
theory, failure of CFT, ligand field theory, 
spectrochemical series, high spin, and low 
spin complexes, Jahn -Taller effect, 
magnetic moments, the origin of color, 
comparison between VBT and CFT, 
molecular orbital theory for octahedral 
complexes. 
 Explain nanoscale. 
 Define nanoparticles. 
 Classify nanoparticles. 
 Explain the property of nanomaterials 
based on catalysis. 
10. Nanochemistry 
Nanoscale, nanotechnology, nanoparticles, 
size-dependent properties of materials, 
classification of nan omaterials, chemical 
and catalytic aspect of nanomaterials 
 
 
Section C: Organic Chemistry 
 
Assessment Targets: 
The candidate will be able to....... 
Contents Marks 
  Define different terms related to basic 
organic chemistry.  
 Explain different phenomena in organic 
compounds. 
 Analyze the stabilities of carbocation’s, 
carbanions, free radicals. 
 Describe the nomenclature of organic 
compounds. 
 Analyze the isomerization (structural, 
geometrical, and conformational ) in 
organic compounds. 
1. Bonding of organic compounds  
Atomic orbitals, covalent bonds, 
hybridization of orbitals and shapes of 
molecules, functional groups, 
homologous series, the nomenclature of 
organic compounds, the polarity of 
molecules, carbocation’s, carbanions- free 
radicals and their stabiliti es, fission of 
covalent bond, change of electron density 
and different effects (Inductive, 
Mesomeric, Electromeric, and 
Hyperconjugation). Resonance, 
Isomerization 
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 Describe the structure, source, 
preparation, physical and chemical 
2. Aliphatic and aromatic 
hydrocarbons 
Alkanes, cycloalkanes, alkenes, dienes,