NTRCA college written syllabus

E:\NTRCA\Exam\17th Exam'20\Written\Syllabus\Written_College level_17th Exam-2020 (1-52 code) (Main).doc    22 
Assessment Targets: 
The candidate will be able to....... 
Contents Marks 
system. 
 Define different terms of 
thermochemistry and 
thermodynamics.  
 Explain different laws of 
thermochemistry. 
 Explain the relation between the 
spontaneity of process and 
enthalpy/entropy/free energy. 
 Solve mathematical problems using 
different laws of thermochemistry.  
3. Thermochemistry and 
thermodynamics 
/Energetics in chemistry  
Work and heat, Internal energy, Three 
laws of thermodynam ics and their 
application, Enthalpy, Enthalpy changes 
in various chemical and physical 
processes, Joule -Thomson effect, 
Entropy, Spontaneity, and reversibility 
of chemical reaction, Lavoisier and 
Hess's law and its application, Bond 
enthalpy, Free energy. 
 Define different terms of phase 
systems. 
 Explain the phase rule. 
 Apply the phase rule in a one-
component system.  
 Apply the phase rule in two 
components system.  
4. Phase equilibrium  
Phase, Components, and degrees of 
freedom. Phase rule, Application in 
one component system like water and 
sulfur, Completely and partially 
miscible liquid pairs.  
 Define different terms related to 
chemical equilibrium and chemical 
kinetics.  
 Explain laws of chemical equilibrium 
and dilute solution.  
 Analyze the degree of dissociation and 
equilibrium constant.  
 Analyze the change of equilibrium with 
changing reaction conditions.  
 Explain the pH of different solutions. 
 Derive the mathematical equation of 
zero, first, second-order reaction, and 
effect of temperature on the reaction 
rate.  
 Solve mathematical problems of the 
equilibrium constant, chemical 
kinetics, and pH.  
5. Chemical equilibrium and 
chemical kinetics  
Equilibrium in chemical reactions and 
the equilibrium law (law of mass - 
action), Kp, Kc and Kx measurements 
and effect of temperature; Pressure of 
Kx measurement, Degree of 
dissociation, Equilibrium constant. 
Ostwald dilution law, Concentration 
change on the dissociation of solids, 
Le- chatelier principle, Solubility 
product, common ion effect, pH and 
buffer solution, buff er action, 
Henderson equation. Rate equation, 
Order of reaction, Molecularity of 
reaction, Rate constant, Zero, first and 
second-order reaction, Effect of 
temperature on the rate of reaction.  
 Define different terms related to 
electrochemistry.  
 Explain the terms related to 
conductance. 
 Explain the construction of different 
electrodes and cells. 
 Explain transport number of 
conductance. 
 Derive the mathematical equation of 
emf of different electrodes and cells.  
 Solve mathematical problems of emf 
of different electrodes and cells. 
 Explain charging, discharging, and uses 
6. Electrochemistry and conductance  
Electrolytes and non -electrolytes, Ionic 
mobility and conductance, 
Electrochemical cells, pH and 
Electrode potentials - emf of cell s, 
Transport number and their 
determination, Electrolytic and 
galvanic cells, Half cells, Different 
types of electrodes, Standard Hydrogen 
electrode, Measurements of electrolytic 
conductance. Rechargeable Battery, 
Fuel cells.